20.The half-life period of a second order reaction products
Options:
independent of the initial concentraiton of A inversely proportional to the initial concentraiton of A directly proportional to the initial concentration of A inversely proportional to the square of the initial concentration of A
21.The langmuir adsorption isotherm is based on the characteristic assumption of
Options:
a flat solid surface a constant heat of adsorption independent of surface coverage zero activation energy for adsorption and desorption ideal gaseous behaviour
22.The energy is quantized in all of the following systems EXCEPT
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an electron in an atomic orbital a particle in free space a particle in a box a simple harmonic oscillator
23.An open vessel at 27C is heated until 60% of the air in it has been expelled. Assuming that the volume of the vessel remains constant, the temperature to which the vessel has been heated is
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600C 477C 750C 1000C
24.Which of the following element act as insulator ?
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Po Pe S Se
25. The ionic radii of and are 95 pm and 181 pm, respectively, The length of the unit cell of is
Options:
276 pm 371 pm 357 pm 552 pm 26. Which is true for the following equilibrium reactions, PCL5, PCl3, Cl2
Options:
On addition of the concentration of decreases Addition of either or will shift the equilibrium towards the left side On removal of the concentration of increases Addition of either or will shift the equilibrium towards the right side
27. Molar masses of three gases and are and respectively. If molar masses are in order the incorrect statement about their most probable velocity is :
Options:
Vmp of A > Vmp of B Vmp of B > Vmp of C Vmp of A < Vmp of B Vmp of B > Vmp of B
28.The langmuir adsorption isotherm is based on the characteristic assumption of
Options:
a flat solid surface a constant heat of adsorption independent of surface coverage zero activation energy for adsorption and desorption ideal gaseous behaviour
29.The order of reaction n, the unitial concentration of the reaction and time required for half of the reaction are related by which equation ?
32. Helium molecule does not exist because Atomic number of He is 2
Options:
number of antibody orbitals in greater than the number of bonding orbitals number of bonding orbitals is guater than number of antibody orbitals its bond and order is zero its bond order is positive
33. The rate and rate constant of a chemical reaction
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are idmtical gromtities are independent of each other are related to rate constant in equal to rate dividend by concentraiton of reactants are related and rate is equal to rate constant dividend by concetration of reactants
34. Rate constants of two reactions at 3535 C are equal. Temperature coefficients of these reactions are 2 and 3 respectively. The rtio of the constants of these reactions at 85C is
Options:
4/27 8/27 32/243 16/81
35. Which gas can be absorbed on a solid to a greater extent ?
Options:
A gas which is non polar A gas having highest critical temp A gas having lowest critical temp A gas having highest critical pressure
1. The ionic radii of and are 95 pm and 181 pm, respectively, The length of the unit cell of is
Options:
276 pm 371 pm 357 pm 552 pm
2. Which is true for the following equilibrium reactions,PCL5, PCl3, Cl2
Options:
On addition of the concentration of decreases Addition of either or will shift the equilibrium towards the left side On removal of the concentration of increases Addition of either or will shift the equilibrium towards the right side
3. Molar masses of three gases and are and respectively. If molar masses are in order the incorrect statement about their most probable velocity is :
Options:
Vmp of A > Vmp of B Vmp of B > Vmp of C Vmp of A < Vmp of B Vmp of B > Vmp of B
4. When treated with conc. gives A. The product A is
Options:
Both the statements are true and statement-2 is a correct explanation for statement1 Both the statements are true but statement-1 is not a correct explanation for statement2 Statement-1 is false and statement-2 is true Statement-2 is false and statement-1 is true
5. The order of reaction n, the unitial concentration of the reaction and time required for half of the reaction are related by which equation
6.Benzoic acid undergoes dimerization in benzene solution, the Vant Hoff factor i is related to the degree of dissociation x of the acid as
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i = (1-x) i = (1+x) i = (1-x/2) i = (1-x/2)
7. The type of hybridization and the shape of the molecule in are respectively
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1 e e^2 e^-2
8. Helium molecule does not exist because (Atomic number of He is 2)
Options:
number of antibody orbitals in greater than the number of bonding orbitals number of bonding orbitals is guater than number of antibody orbitals its bond and order is zero its bond order is positive
9. The rate and rate constant of a chemical reaction,
Options:
are idmtical gromtities are independent of each other are related to rate constant in equal to rate dividend by concentraiton of reactants are related and rate is equal to rate constant dividend by concetration of reactants
10. Rate constants of two reactions at 3535 C are equal. Temperature coefficients of these reactions are 2 and 3, respectively. The rtio of the constants of these reactions at 85C is
Options:
4/27 8/27 32/243 16/81
11. Which gas can be absorbed on a solid to a greater extent
Options:
A gas which is non polar A gas having highest critical temp A gas having lowest critical temp A gas having highest critical pressure
12. Which gas can be absorbed on a solid to a greater extent
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In solutions where the solute associates the elevation in B.P is more In distribution reactions the decrease in Freezing point is less Absolute enthalpy of a compound is equal to heat of formation of that compound The units of rate of a third order reaction are lit per second
13.Identify the wrong statement in the following :
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Feron used as refrigeratnt is dichlorodifluro methane A deutron is a nucleus containing a neutron and a proton Zeolite is an example of 3-dimensional silicate The anhydride of acid is HCL0 is Cl2O3
14.Pick the wrong statement from the following
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The most common measurement of atmospheric particulate is the particulate matter and is referred to as PM PM is measured in lenth of DDT is the one of the most famous is sectide . The full name of dichloro diphenyl tnchloro ethane Chlorofluoro carbons are good refrigerants
15. A liquid is in equilibrium with its vapor at its boiling point. On the average the molecules in the two phases have equals
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inter molecular forces potential energy total energy kinetic energy
16. In crystalobaltie, the coordination number of silicon is
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Two Three Six Four
17.Knowing that the startered reduction potential for lithium is -3.045 V and that of sodium -2.714 V, which of the following statements is correct ?
Options:
This correctly shows that the reactivity of the elements decreases down the group. This is anamalous and arises from small size and very large hydration energy of the free gaseous lithium ion as compared to with of sodium. This is anomalous and anies from large size and consequently large hydration energy of the free gaseous sodium ion as compared to that of lithium This is anomalous and arrises from small size consequently low hydration energy of free gaseous lithium ion as compared to with of sodium.
18.Upon adding solid sodium acetate to an aqueous acetic acid solution, there is
Options:
an increases in the degree of ionization of acetic acid an increases in the ionization constant of acetic aci a decrease in the OH- concentration of the solution a decrease in the OH+ concentration of the solution.
19.Which are of the following pairs of chemical compounds does Not give a buffer solution on suitable mixing ?
Options:
Ammonium chloride and ammonium hydroxide Acetic acid and sodium acetateto with of sodium. Hydrochloric acid and aniline hydrochloride Sodium carbonae and sodium hydrogen carbonate
20.The half-life period of a second order reaction products
Options:
independent of the initial concentraiton of A inversely proportional to the initial concentraiton of A directly proportional to the initial concentration of A inversely proportional to the square of the initial concentration of A